Attachment 1: Reference Source Testing Methods

This Attachment contains a list of acceptable methods for the measurement of emissions of air pollutants from stationary sources when such emission data are required for the purpose of determining compliance with the Environmental Protection Act of the Province of Ontario and the regulations thereunder.

These methods comprise the most up-to-date procedures available at the date of issue of this Code; however, as new and improved techniques become available, the most current version of the methods shall be used when conducting source testing.

The stack gas parameters determination are covered in detail in Parts B to E (Methods ON-1 to ON-4) of this code, and are commonly used for each stack gas test. However, these four methods are often performed simultaneously when using Method ON-5 or modified Method ON-5 sampling trains.

For contaminants without established reference test methods the proponent should demonstrate to the satisfaction of the Source Assessment Specialist that the stack gas sampling, sample recovery and analysis accurately represent what is being discharged to the atmosphere.

1. List of Reference Source Testing Assessment Methods for Contaminants Listed in O.Reg. 419/05

Item CAS No. Contaminant Reference Method
(Source Testing)
1. 75-07-0 Acetaldehyde CARB Method 430
2. 64-19-7 Acetic Acid NIOSH Method 1603 - Modified
3. 67-64-1 Acetone US EPA SW-846 Method 0030
4. 74-86-2 Acetylene OSHA Chemical Sampling Information
5. 79-06-1 Acrylamide OSHA Method 21 - Modified
6. 107-13-1 Acrylonitrile US EPA SOP# 1704
7. 7664-41-7 Ammonia US EPA Method CTM-027
8. 7440-36-0 Antimony US EPA 40CFR60 Method 29
9. 7784-42-1 Arsine NIOSH Method 6001 - Modified
10. 7440-41-7 Beryllium and compounds US EPA 40CFR60 Method 29
11. 7440-42-8 Boron US EPA 40CFR60 Method 29
12. 10294-33-4 Boron Tribromide OSHA CSI Method – Modified
13. 10294-34-5 Boron Trichloride US EPA 40CFR60 Method 29, or US EPA 40CFR60 Method 26
14. 7637-07-2 Boron Trifluoride OSHA CSI Method – Modified
15. 7726-95-6 Bromine US EPA 40CFR60 Method 26
16. 7440-43-9 Cadmium US EPA 40CFR60 Method 29
17. 1305-62-0 Calcium Hydroxide US EPA 40CFR60 Method 29
18. 1305-78-8 Calcium Oxide US EPA 40CFR60 Method 29
19. 1333-86-4 Carbon Black OSTC Method ON-5
20. 75-15-0 Carbon Disulphide Environment Canada Method EPS 1/RM/6
21. 630-08-0 Carbon Monoxide US EPA 40CFR60 Method 10
22. 56-23-5 Carbon Tetrachloride US EPA SW-846 Method 0030
23. 7782-50-5 Chlorine US EPA 40CFR60 Method 26
24. 10049-04-4 Chlorine Dioxide NCASI Technical Bulletin 520
25. 67-66-3 Chloroform US EPA SW-846 Method 0030
26. - Chromium - Speciation US EPA SW846 Method 0061
27. 7440-47-3 Chromium – Total US EPA 40 CFR 60 Method 29
28. 7440-50-8 Copper US EPA 40CFR60 Method 29
29. 1319-77-3 Cresols NIOSH Method 2546 - Modified
30. 17702-41-9 Decaborane OSHA CSI Method – Modified
31. 117-81-7 Di(2-ethylhexyl) Phthalate NIOSH Method 5020 – Modified
32. 19287-45-7 Diborane NIOSH Method 6006 – Modified
33. 131-15-7 Dicapryl Phthalate OSHA Method 104 – Modified
34. 106-46-7 Dichlorobenzene, 1,4- Environment Canada Method EPS 1/RM/2
35. 624-92-0 Dimethyl Disulphide Environment Canada Method EPS 1/RM/6
36. 75-18-3 Dimethyl Sulphide Environment Canada Method EPS 1/RM/61/RM/6
37. 117-84-0 Di-n-Octyl Phthalate OSHA Method 104 – Modified
38. - Dustfall ASTM Method D1739-98 (2004)
39. 141-78-6 Ethyl Acetate US EPA 40CFR60 Method 18 -Tedlar® Bag - GC-FID
40. 140-88-5 Ethyl Acrylate NIOSH Method 1450 - Modified
41. 100-41-4 Ethyl Benzene US EPA SW-846 Method 0030
42. 60-29-7 Ethyl Ether NIOSH Method 1610 - Modified
43. 107-06-2 Ethylene Dichloride US EPA SW-846 Method 0030
44. 1309-37-1 Ferric Oxide US EPA 40CFR 60 Method 29
45. 7664-39-3 Fluorides (as HF) - Gaseous (Growing Season) US EPA 40CFR60 Method 13B
46. 7664-39-3 Fluorides (as HF) - Total (Growing Season) US EPA 40CFR60 Method 13B
47. 7664-39-3 Fluorides (as HF) - Total (Non-Growing Season) US EPA 40CFR60 Method 13B
48. 50-00-0 Formaldehyde CARB Method 430
49. 64-18-6 Formic Acid NIOSH Method 2011 - Modified
50. 98-01-1 Furfural NIOSH Method 2529 - Modified
51. 98-00-0 Furfuryl Alcohol NIOSH method 2505 - Modified
52. 7647-01-0 Hydrogen Chloride US EPA 40CFR60 Method 26/26A
53. 7783-06-04 Hydrogen Sulphide US EPA 40CFR60 Method 11
54. 15438-31-0 Iron (metallic) US EPA 40CFR60 Method 29
55. - Isocyanates Speciation US EPA CTM-036
56. 98-82-8 Isopropyl Benzene (cumene) US EPA SW-846 Method 0030
57. 7439-92-1 Lead US EPA 40CFR60 Method 29
58. 7439-93-2 Lithium US EPA 40CFR60 Method 29
59. 7580-67-8 Lithium Hydrides US EPA 40CFR60 Method 29
60. 1309-48-4 Magnesium Oxide US EPA 40CFR60 Method 29
61. 74-93-1 Mercaptans Environment Canada Method EPS 1/RM/6
62. 7439-97-6 Mercury (Hg) US EPA 40CFR60 Method 29
63. 7439-97-6 Mercury (Hg) US EPA 40CFR60 Method 30B
64. 7439-97-6 Mercury (as Hg) – alkyl compounds US EPA 40CFR60 Method 101
65. 67-56-1 Methanol (Methyl Alcohol) US EPA 40CFR60 Method 308
66. 96-33-3 Methyl Acrylate NIOSH Method 2537 - Modified
67. 71-55-6 Methyl Chloroform (1,1,1- Trichloroethane) US EPA SW-846 Method 0030
68. 78-93-3 Methyl Ethyl Ketone (2- Butanone) US EPA SW-846 Method 0030
69. 108-10-1 Methyl Isobutyl Ketone US EPA SW-846 Method 0030
70. 80-62-6 Methyl Methacrylate NIOSH Method 2537 - Modified
71. - Milk Powder OSTC Method ON-5
72. - Mineral Spirits (Naphthas) NIOSH Method 1550 - Modified
73. 74-89-5 Monomethyl Amine OSHA Method 40 – Modified
74. 142-82-5 n-Heptane US EPA SW-846 Method 0030
75. 7440-02-0 Nickel US EPA 40CFR60 Method 29
76. 13463-39-3 Nickel Carbonyl NIOSH Method 6007 - Modified
77. 7697-37-2 Nitric Acid US EPA Method CTM027 – Modified
78. 139-13-9 Nitrilotriacetic Acid BC Laboratory Methods Manual
79. 10102-44-0 Nitrogen Oxides US EPA 40CFR60 Method 7E
80. 10028-15-6 Ozone OSHA Method 214 – Modified
81. 19624-22-7 Pentaborane OSHA CSI Method - Modified
82. 108-95-2 Phenol US EPA 40CFR60 Method 318
83. 75-44-5 Phosgene US EPA Draft Method
84. 7664-38-2 Phosphoric Acids CARB Method 421
85. 85-44-9 Phthalic Anhydride OSHA Method 90 – Modified
86. 78-87-5 Propylene Dichloride NIOSH Method 1013 - Modified
87. 75-56-9 Propylene Oxide NIOSH Method 1612 - Modified
88. 7440-22-4 Silver US EPA 40CFR60 Method 29
89. 100-42-5 Styrene US EPA SW-846 Method 0030
90. 7446-09-5 Sulphur Dioxide US EPA 40CFR60 Method 6C
91. 7664-93-9 Sulphuric Acid US EPA 40CFR60 Method 8
92. - Suspended Particulate Matter (< 44 µm Diameter) OSTC Method ON-5
93. 13494-80-9 Tellurium (except hydrogen telluride) US EPA 40CFR60 Method 29
94. 109-99-9 Tetrahydrofuran NIOSH Method 1609 - Modified
95. 7440-31-5 Tin US EPA 40CFR60 Method 29
96. 7440-32-6 Titanium US EPA 40CFR60 Method 29
97. 108-88-3 Toluene US EPA SW-846 Method 0030
98. 584-84-9 Toluene Di-isocyanate, 2,4- US EPA CTM-036
99. 79-01-6 Trichloroethylene (TCE) US EPA SW-846 Method 0030
100. 76-13-1 Trifluorotrichloroethane US EPA SW-846 Method 0030
101. 7440-62-2 Vanadium US EPA 40CFR60 Method 29
102. 75-01-4 Vinyl Chloride US EPA 40CFR60 Method 106
103. 75-35-4 Vinylidene Chloride (1,1-Dichloroethene) US EPA SW-846 Method 0030
104. 1330-20-7 Xylenes US EPA SW-846 Method 0030
105. 7440-66-6 Zinc US EPA 40CFR60 Method 29

O. Reg. 419/05; O. Reg. 605/05.

ASTM
The American Society for Testing and Materials
BC
British Columbia
CARB
State of California Air Resources Board
CSI
OSHA Chemical Sampling Information
NIOSH
US National Institute for Occupational Safety and Health
OSHA
US Occupational Safety & Health Administration
OSTC
Ontario Source Testing Code
SOP
Standard Operating Procedure
US EPA
United States Environmental Protection Agency

2. List of Reference Source Testing Assessment Methods for Contaminants Not Listed in O. Reg. 419/05

Item Contaminant Reference Method (Source Testing)
1. Aldehydes CARB Method 430
2. Acetic Acid NIOSH Method 1603 - Modified
3. Acetone US EPA SW-846 Method 0030
4. Asbestos CARB Method 427, or Environment Canada Method EPS 1-AP-75-1
5. Benzene CARB Methods 410A/410B
6. Carbon Dioxide US EPA 40 CFR60 Method 3A
7. Carbon Disulphide US EPA 40 CFR60 Method 15
8. Carbon Monoxide US EPA 40 CFR60 Method 10
9. Carbonyl Sulphide Environment Canada Method EPS 1/RM/2
10. Chlorobenzene Environment Canada Method EPS 1/RM/2
11. Chlorophenol Environment Canada Method EPS 1/RM/2footnote 1
12. Chromium Speciation US EPA SW846 Method 0061
13. Chromium - Total US EPA 40 CFR60 Method 29
14. Cyanide CARB Method 426
15. Dioxins Environment Canada Method EPS 1/RM/2footnote 2
16. Ethylene Oxide CARB Method 431
17. Furans Environment Canada Method EPS 1/RM/2footnote 2
18. Hydrogen Halides US EPA 40CFR60 Methods 26/26A
19. Hydrogen Sulphide US EPA 40CFR60 Method 11
20. Isocyanates Speciation US EPA CTM-036
21. Metals US EPA 40CFR60 Method 29
22. Mercury Speciation ASTM Method D6784-02
23. Microbial Survivability Test for Medical Waste Incinerator Emissions US EPA Method CTM-026
24. Odour OSTC Method ON-6
25. Opacity US EPA 40CFR60 Method 9
26. Orthophosphate Alberta Method 45050/45051
27. Oxygen US EPA Methods 3A
28. PM10 US EPA 40CFR60 Method 201A
29. PM10/PM2.5 US EPA Method CTM-040
30. Particulate Matter (Condensable) US EPA 40CFR60 Method 202
31. Polonium 210 US EPA 40CFR60 Method 111
32. Polychlorinated Dibenzo-p-Dioxins Environment Canada Method EPS 1/RM/2footnote 2
33. Polychlorinated Dibenzo Furans Environment Canada Method EPS 1/RM/2footnote 2
34. Polychlorinated Biphenyls (PCBs) Environment Canada Method EPS 1/RM/2
35. Polynuclear Aromatic Hydrocarbons Environment Canada Method EPS 1/RM/2footnote 3
36. Total Gaseous Non-methane Organics US EPA Method 25
37. Total Gaseous Organics US EPA Method 25A
38. Total Reduced Sulphur (TRS) – Non-Speciated US EPA Method
38. Total Reduced Sulphur (TRS) - Speciated Environment Canada Method EPS 1/RM/6
39. Urea Alberta Method 47575
40. Volatile Organic Constituentsfootnote 4 US EPA SW-846 Method 0030
Alberta
Alberta Environment (Canada)
CARB
State of California Air Resources Board
US EPA
United States Environmental Protection Agency
OSTC
Ontario Source Testing Code

Attachment 2: Guidebook to Prepare a Pre-Test Plan Document

Acknowledgement

This document is based on the U.S. Environmental Protection Agency’s “Guidebook on the Preparation and Review of Site-Specific Test Plans”. It has been adapted to reflect requirements specific to Ontario, e.g., references to Certificates of Approval.

Purpose And Use Of Guidebook

The purpose of this guidebook is to provide a standard format for preparing pre-test plans for compliance source test programs such as those required by Certificates of Approval, Provincial Officers’ Orders and notices issued by the Ontario Ministry of Environment.

The same guidebook format should be used for source test programs if the results are intended to be accepted as representative and accurate by the Ministry. Any tests done for these reasons and to this level of Quality Assurance/Quality Control (QA/QC) are referred to as being of “compliance quality.”

A properly prepared pre-test plan should include written descriptions, summary tables, and figures that encompass all aspects in the planning of an emissions test program. The pre-test plan is to provide the information necessary to determine whether a testing organization understands the objectives of the test and whether the test includes appropriate procedures to accomplish these objectives.

The pre-test plan guidebook has been developed to facilitate the preparation of pre-test plans by outlining the information required. Following this guidebook will make the preparation of the pre-test plan easier and more effective.

Summary Of Source Testing Procedure

  1. A compliance test is a source test conducted for the purpose of determining compliance with the Environmental Protection Act of Ontario or the regulations promulgated thereunder, performed and reported in accordance with the requirements of Part A of this code. The Ministry must be advised of any proposed compliance testing prior to testing and supplied with a term of reference which should include at least relevant process and test information. If required, a Ministry official must be allowed to tour the process, inspect the sampling site and witness the sampling tests. It must be demonstrated that the testing was performed at process conditions effecting the maximum pollutant emissions, e.g., at normal maximum production rates excluding process upsets, and that the test results truly represent the emissions from this source. A complete final report must be submitted to the Ministry.
  2. Three replicate samples must be taken over a sufficient time to represent the source accurately. Refer to this Code’s Parts A through F for specific requirements.
  3. Under the Ministry’s normal practice, compliance source testing may be witnessed by the Ministry, if deemed necessary.
  4. Following the Ministry’s approval of the pre-test plan, the Company shall notify the Ministry in writing of the location, date and time of any impending Source Testing required for compliance, at least fifteen (15) days prior to the Source Testing.
  5. In order to avoid unnecessary and unproductive time of witnessing staff on-site, it is important to keep this Ministry informed of any changes or delays in starting times for source tests. While downtime of equipment may be unforeseeable in some cases, an effort to minimize this during the time our staff is on-site would be greatly appreciated. The appropriate regional office should be contacted to obtain the appropriate telephone number of Ministry staff looking after that specific plant or geographical area where the plant under study is located.
  6. The emission test report resulting from the source testing should be submitted to the Ministry.

Download Guidebook to Prepare a Pre-Test Plan Document

Attachment 3:Recommended Qualifications for Stack Sampling Team

It is essential for the production of valid test data that the emissions measurement program be performed by qualified personnel using proper test equipment.

The source sampling team should consist of no less than two persons to perform the tests at the sampling site. A third person should be included when sampling variable rate processes, to correlate the sampling activity with the manufacturing process. For multi-stack sampling, the team should be increased accordingly.

One of the two persons shall be the source testing supervisor or leader, who will ensure that sampling is conducted properly and that the process is operating at the maximum or required production rate.

The source testing supervisor or leader must have sufficient experience and understanding of industrial processes and source testing to perform activities outlined in the introduction. The supervisor or leader must have an educational background in engineering, engineering technology or environmental science, or at least two (2) years of source testing field experience conducting source testing.

The remaining members of the source testing team should have sufficient experience to prepare and operate source sampling trains in a competent manner. He or she should have successfully completed in-house or external training on source testing and have previous field experience in source testing using the reference methods mentioned in this code.

Other stack testing team members with no previous experience in source testing must have successfully completed an in-house or external training on source testing, followed by at least two week period of source testing field observation. ASTM D7036 can be used as a general guide on determining personnel competency to carry out sampling and analysis of stationary source testing programs.

References

  1. Ministry of the Environment, Province of Ontario, Source Testing Code, Version 2, November 1980.
  2. United States Environmental Protection Agency, Preparation and Review of Site-Specific Test Plans, December 1991.

Footnotes

  • footnote[1] Back to paragraph This method must be used in conjunction with Environment Canada’s Method 1/RM/3 and the Methodology for Organic Analysis - NITEP/Mid-Connecticut Combustion Test.
  • footnote[2] Back to paragraph This method must be used in conjunction with Environment Canada’s Method 1/RM/3 and Report EPS 1/RM/23.
  • footnote[3] Back to paragraph This method must be used in conjunction with Environment Canada’s Methodology for Organic Analysis - NITEP/Mid-Connecticut Combustion Test.
  • footnote[4] Back to paragraph Refer to the reference method for a list of constituents that can be sampled with this method.